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One atmosphere is appx. 14.7 psi, so inflating to even 45 psi with nitrogen still leaves close to 25% air unless the space inside the tire is purged first. Give them this fact and then ask them to justify the cost. If they say they purged the tires, ask them to explain the process.
John, here's the math in my head... Equal pressure in the tire (zero psi) is one atmosphere. 15psi should then roughly double the mass of air inside the tire, or two atmospheres. So at 45 psi, you've roughly quadupled the total mass of air. Granted, with the total of gasses not nitrogen, you then end up with 25% of 22%, or 5.5% other than Nitrogen. Deflate the tire and reinflate it back to 45psi, and you reduce that by another 75% with each cycle.
But if the average tire sales man knows that, they're overqualified for their job!