Also....... Balsa...
By the way, you can make a large model (lets say a brief case size model) by finding a mock-up core (old box, etc), then covering that with bondo, and shaping to finish. You can also go with surf board foam, sculpt it to roughly the shape, and then coat it with resin and bondo, and they finish, then pull a mold from it.
If you have never worked with resin and fiberglass though, you'd probably not want to do this.
If you create an amazing exterior mockup, you can go to a fiberglass shop (really look hard at finding a good shop, like a boat shop that builds boats, etc, and are reliable), and have them make molds and a model from that.. Then you only need to paint and finish.
Plaster is really amazing. You can sculpt it well with sand paper, blocking, etc. Then coat with primer and then use spray on bondo coatings and finish. You can make plaster molds, but plaster 'super heats' when it goes off and turns solid, so you have to be careful as it will burn/warp your plug (part you make the mold from). But its far better then using fiberglass. There are some cool new pour type mold materials you can buy at hobby stores, but they are flexible, so you need to have them in wooden former boxes to keep their shape. After a while, they deteriorate, so you need to keep your plug in a safe place so you can remold from it..
Bill